Kinetic control in noncovalent synthesis: regioselective ligand exchange into a hydrogen bonded assembly.

نویسندگان

  • Jeffery T Davis
  • Mark S Kaucher
  • Frank W Kotch
  • Maura A Iezzi
  • Bryna C Clover
  • Katherine M Mullaugh
چکیده

This paper illustrates the use of a kinetically controlled exchange reaction to effect regioselective modification of a hydrogen-bonded assembly. Both the bound anion and cation can control the exchange of ligand into the different layers of a synthetic G-quadruplex.

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عنوان ژورنال:
  • Organic letters

دوره 6 23  شماره 

صفحات  -

تاریخ انتشار 2004